We have discussed acetone as a petrol additive to increase octane. A lot of the effect depends on the engine. You will need to mix the acetone properly and there is a risk that plastic pipes and seals will be dissolved by adding it so personally I decided not to risk it.
Some engines run more economically on higher octane fuel but it depends a lot on how the engine works. A closed loop engine will trim itself and push nearer to the knock threshold. Higher compression engines responds better and jap cars seem to love high octane fuel.